DescriptionQuantum ideal gas chemical potential 3d.svg
English: Chemical potential of classical ideal gas and quantum ideal gases (Fermi gas, Bose gas) as a function of temperature, for a fixed density of particles. This is for the case of non-relativistic (massive, slow) particles in three dimensions.
A few features can be seen:
As temperature increase, the Fermi and Bose gases approach the classical gas line, gradually.
The classical gas has an interesting non-monotonic behaviour, but the quantum gases are monotonic (note that in 1D, however, the Fermi gas is also non-monotonic).
The Fermi gas is always higher chemical potential, and Bose gas is lower chemical potential, compared to classical ideal gas.
The * marker indicates the upper temperature of Bose condensation. Moving below this temperature, the chemical potential is pinned to ε0, which is the energy of a particle at rest (i.e. the per-particle potential energy).
The Fermi gas at low T (far below Fermi temperature TF) saturates to a value ε0 + εF. This extra εF=kTF is its Fermi energy.
The figure has been scaled in a way that the particle degeneracy factor, density, mass, etc. are all factored out and irrelevant.
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Captions
Chemical potential of classical ideal gas and quantum ideal gases (Fermi gas, Bose gas) in three dimensions as a function of temperature, for a fixed density of particles.